Brad Pitt is no longer the only man in Angelina Jolie’s life.  Louis Vuitton reportedly paid the mega-star $10 million to appear in a series of ads for an upcoming campaign. The actress slash philanthropist’s flawless mug will be one of many famous faces the French luxury label has utilized to market their coveted goods.

A flitting rumor lands famed photographer Annie Leibovitz behind the lens for the next few weeks of shooting starting today in the Kingdom of Cambodia, home to adopted son Maddox. According to Phemon Penh Post, CEO of the Cambodian Film Commission, Cedric Eloy, confirmed yesterday that his organization will be on board for the label’s advert with the Jolie in Siem Reap but would not release any details claiming it would make a rushed situation more hectic. Jolie, he claimed, was slated to set foot in Cambodia today.

The print-only promotions will launch globally this summer when she will join other celebrity names such as Scarlett Johannsen, Jennifer Lopez, and Madonna.

Jolie, with aid from jeweler Robert Procop, has recently dabbled in the fashion industry with the addition of a high-end jewelry line.  Pieces starting at $4000 benefit the Education Partnership for Children of Conflict.  A more affordable retail line will hit the stores in the second half of this year.

The collection named The Style of Jolie, is slated to be shown next in Monaco and previously available to be viewed by invitation only through  Julien’s Gallery and Auctions in Beverly Hills.

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